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Supertopics:
Frozen Food as Less Healthy
Myrosinase (Cruciferous Enzyme) for Making Sulforaphane

Blanching Broccoli for Freezing Destroys Myrosinase

Documents:
frozen broccoli lacks the enzyme to make sulforaphane
webEdward B. Dosz, Elizabeth H.Je...Journal of Functional Foods2013-02-19
blanched frozen broccoli lacks the myrosinase enzyme
webSaha S, Hollands WMol Nutr Food Res2012-10-27